WEBThe X c of coal during the liquefaction process generally increases with temperature and time, but Fig. 3 (a)(c) indies that the X c of three coals at 455 °C is lower compared to that at 440 °C. This suggests that condensation occurs during the coal liquefaction process, leading to the formation of coke.
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WEB4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur). ...
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WEBSep 1, 2011 · Highlights A novel liquefaction and distillation process is designed for oxygen bearing coalbed methane. Oxygen contained in coalbed methane is removed in distillation process. Flammability limits are analyzed for the whole operation process. We find explosion hazard may exist in distillation tower. Effective measures are proposed to .
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WEBFeb 1, 2000 · Effect of reaction temperature on hydrotreatment of a recycle solvent in the NEDOL coal liquefaction process was studied from the data obtained by the operation of a 150 t/d pilot of the recycle solvent was carried out under a hydrogen pressure of 100 kg/cm 2 G over Ni–Mo/Al 2 O 3 alyst in a fixed bed reactor. As the .
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WEBMar 24, 2009 · Coal liquefaction technology is a process for converting coal to liquid fuels by dissolving coal in an organic hydrogendonor solvent in the presence of hydrogen and a alyst under high ...
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WEBSep 15, 2001 · The brown coal liquefaction (BCL) process is a twostage liquefaction (hydrogenation) process developed for Victorian brown coal in Australia. The BCL process has a solvent deashing step to ...
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WEBApr 1, 2022 · After direct coal liquefaction process, the inherent sodium species in sodiumrich coals will be enriched in direct coal liquefaction residue. In this work, to provide potential guidance for better utilization of sodiumrich direct coal liquefaction residue, alytic effects of the inherent sodium species on gasifiion reactivity of .
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WEBFeb 1, 2006 · The coal residue from alytic liquefaction at 450 °C and 10 MPa which had lower sulfur content (%) and higher heating value ( MJ/kg) will be considered for use subsequently in a gasifiion process. Furthermore, the coal residue or char can be used in fluidized combustion, in gasifiion or for hydrogen production since such ...
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WEBSep 1, 2015 · Typical liquefaction process is performed at 400 °C for 60 min under 5 MPa H 2 (initial pressure) in 2:1 (solvent: coal) tetralin solvent with 5% FeS + S (an equimolar mixture of FeS and S) as alyst. A detailed procedure of hydroliquefaction and separation can be seen elsewhere [31]. The AS and PA obtained by a batch .
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WEBOct 1, 1984 · Process slurries emanating from reactors generally contain 5 to 10 wt.% of solids. Solid—liquid separation processes must be used to separate the mineral residue and unconverted carbon from liquefied coal. Difficulties in removing those solid components represent a major obstacle to economic production of liquefied coal products.
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WEBNov 1, 2019 · In this study, a coalfired power plant followed by an absorption postcombustion CO 2 capture unit and a CO 2 liquefaction unit is simulated; the schematic of Fig. 1 illustrates the block diagram of the subsystems and shows the streams that are between these units. Also, Fig. 2 indied the process flow diagram of the best .
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WEBBrown coal liquefaction technology is intended realize the liquefaction of brown coal of Victoria, Australia, with the object of utilizing it as an energy resource. Research and Development was started in 1981 with a 50 t/d pilot plant in Victoria province. Fig. shows the process. The initial goals of the project, 50% liquid fuel yield ...
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WEBOn the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
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WEBThe Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasifiion.
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WEBA novel liquefaction and distillation process has been proposed and designed for the typical oxygenbearing coalbed methane (CBM), in which the impurities of the oxygen and nitrogen components are removed in the distillation column.
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WEBFeb 1, 2024 · To understand the formation of residues and its relation with the vitrinite structure and the products yield in direct coal liquefaction (DCL), a high vitrinite lowrank coal, Naomaohu (NMH), is studied at 380–460 °C in the presence of tetrahydronaphthalene and absence of a alyst. ... Direct coal liquefaction (DCL) is an important process ...
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WEBMay 1, 2023 · 1. Introduction. Direct coal liquefaction (DCL) is one of the routes to directly convert coal to oils and chemicals [1], [2], [3].Its core reactions include the generation of radical fragments of a wide range of molecular sizes by cleavage of weak covalent bridge bonds in coal followed by hydrogenation of the radical fragments to form products, such .
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WEBAug 18, 2010 · Coalbed methane (CBM) is a type of clean energy. However, most oxygenbearing CBM have not yet to be utilized due to limited techniques, and when utilized, the discharged gas leads to resource wastage and environment pollution. In this paper, a liquefaction process is proposed and designed for the specified oxygenbearing CBM .
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WEBThis paper presents a brief state of the art review of direct coal liquefaction. The review includes important pilot scale processes available for the liquefaction an a brief description of the structure of coal and the chemistry, mechanism and available lumped kinetic models for the liquefaction process. It also includes some discussions on ...
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WEBHydrothermal liquefaction (HTL) is a thermal depolymerization process used to convert wet biomass, and other macromolecules, into crudelike oil under moderate temperature and high pressure. The crudelike oil has high energy density with a lower heating value of MJ/kg and 520 wt% oxygen and renewable chemicals. The process has also .
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WEBFeb 15, 2024 · Based on the multistage liquefaction process, asphaltene was prepared from Hongliulin coal and deeply liquefied with NiCoMo, CoMo, and Fe2 O 3 alysts. The yields of each component were obtained. Ultimate analysis, FTIR and XPS was used to investigate the conversion of oxygenic structure. The results showed that the ability to .
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WEBAug 10, 2014 · This disparity with respect to the distribution is mainly due to the different coal sources and the solid–liquid separation techniques used to recover the residue from the coal liquefaction process [11]. Download : Download highres image (89KB) Download : Download fullsize image; Fig. 1. The distribution of solvent extraction .
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WEBPetroleum gas production. For producing petroleum gas, the optimal advanced oil processing ratio is 20:5:17 (advanced oil processing : heavy oil cracking : light oil cracking), and 8:2:7 is close enough. Using coal liquefaction, the ratio is 60:39:55 (coal liquefaction : heavy oil cracking : light oil cracking), and 12:8:11 is close enough.
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WEBNov 1, 1981 · To determine the effects and relative importance of process variables in coal liquefaction, ... a typical coal liquefaction unit. The rvalue of Powhatan coal heated to 500 in a vacuum is , typical of re aromatic hydrocarbons and above the 0value of the free electron, suggesting that conductivity effects are not important with ...
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WEBNov 21, 2000 · Direct coal liquefaction test plants have been constructed and successfully operated under subsidies from the New Energy and Industrial Technology Development Organization. To analyze the data, which had been collected on these plants, a simulator was constructed for the material and enthalpy balances in the preheaters and reactors. .
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WEBJun 1, 2017 · 1. Introduction. The first commercial direct coal liquefaction (DCL) plant after World War II was built by Shenhua Group, China. The main characteristics of Shenhua DCL process include a twostage process, a nanosize iron alyst and a hydrogenated recycle solvent which contain hydrogen donor solvent and nondonor polycyclic aromatic .
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WEBMar 27, 2023 · Background Indirect coal liquefaction differs fundamentally from direct coal liquefaction in that the coal is first converted to a synthesis gas (a mixture of H2 and CO) which is then converted over a alyst to the final product. Figure 279 presents a simplified process flow diagram for a typical indirect coal liquefaction process.
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WEBFeb 1, 2000 · The 150t/day NEDOL coal liquefaction pilot plant (PP) has validated the superior technical features with a highly active liquefaction alyst and hydrogen donor solvent. ... was formed to develop energy substituting for oil in 1974 and the NEDOL bituminous coal liquefaction process has been developed as one of the RD projects .
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WEBDec 1, 2022 · Nowadays, to reduce the cost of coal liquefaction and to produce a new liquid fuel alternative to petroleum, it is considered a more convenient method to liquefy coal and biomass together instead of solely coal liquefaction. ... Depending on the liquefaction process conditions, the carbon, hydrogen, sulfur, nitrogen, and oxygen .
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